I would wager that it has a lot to do with the fact that those three zanpakutou have been shown the least in the series. We have no idea what Kyouraku or Ukitake's zanpakuto can do and all we've seen from Unohana's is the healing monster thing. Filler can't really expand on stuff that hasn't been revealed. That being said, those three are also (seemingly) the oldest captains other than Yamamoto. If we assume that Shinigami (and thus zanpakuto) get more and more powerful with time then those three are probably the most powerful zanpakuto around. For sealing someone as badass as the Captain-Commander I think it makes sense that Muramasa would have to use the best to pull it off.Originally Posted by The Chancellor