The technique where he rooted Kakashi and the one where he attacks pain from underground, if i recall correctly he called them Douton something, i *think* he used Fire ball against Naruto and Sakura, also, he uses all 5 elements in the Ultimate Ninja series, apparentelly, the abilities used there are Canon.
Quick quote from Narutowiki.
Individually, he is able to perform earth-based techniques with great detail in their shape, and is able to perform water-based techniques without an existing water source nearby. He has also been shown (in the anime) using fire-based techniques, and he is otherwise at least knowledgeable enough with Wind Release to help train Naruto in its use.